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A point-of-use electrochemical phosphate sensor is achieved with electrodeposited mixed-valence molybdenum oxide on flexible electrodes, enabling selective detection in complex aqueous environments. 

The various isotopes of thorium offer oceanographers tools for tracking particulate matter in the ocean across multiple timescales. To learn about the cycling of trace elements in the ocean, in this perspective we focus on the latest applications of thorium’s longest-lived naturally occurring isotopes: 232Th, 230Th, 228Th, and 234Th. From desert dust to marine snow to sediment porewaters, thorium measurements can be used to derive rates of trace element input and removal, using the assumptions of radioactive disequilibrium. Opportunities exist to fine tune and improve the application of these already versatile stopwatches, but GEOTRACES-era data clearly demonstrate their utility. 

We investigate the potential to detect Higgs boson decays to four bottom quarks through a pair of pseudoscalars, a final state that is predicted by many theories beyond the Standard Model. For the first time, the signal sensitivity is evaluated for the final state using the vector boson fusion (VBF) production with and without an associated photon, for the Higgs at $m_H=125\mathrm{GeV}$, at hadron colliders. The signal significance is $0.5\sigma$to $6\sigma$, depending on the pseudoscalar mass $m_a$, when setting the Higgs decay branching ratio to unity, using an integrated luminosity of $150{\mathrm{fb}}^{-1}$at $\sqrt{s}=13\mathrm{TeV}$. This corresponds to an upper limit of 0.3, on the Higgs branching ratio to four bottom quarks, with a nonobservation of the decay. We also consider several variations of selection requirements—input variables for the VBF tagging and the kinematic variables for the photon—that could help guide the design of new triggers for the Run-3 period of the LHC and for the HL-LHC. Published by the American Physical Society2024 

Abstract Fully and accurately reconstructing changes in oceanic productivity and carbon export and their controls is critical to determining the efficiency of the biological pump and its role in the global carbon cycle through time, particularly in modern CO₂source regions like the eastern equatorial Pacific (EEP). Here we present new high-resolution records of sedimentary²³⁰Th-normalized opal and nannofossil carbonate fluxes and [²³¹Pa/²³⁰Th]xs ratios from site MV1014-02-17JC in the Panama Basin. We find that, across the last deglaciation, phytoplankton community structure is driven by changing patterns of nutrient (nitrate, iron, and silica) availability which, in turn, are caused by variability in the position of the Intertropical Convergence Zone (ITCZ) and associated changes in biogeochemical cycling and circulation in the Southern Ocean. Our multi-proxy work suggests greater scrutiny is required in the interpretation of common geochemical proxies of productivity and carbon export in the EEP. 

Abstract The 4 ⁢ N {4N} -carpets are a class of infinitely ramified self-similar fractals with a large group of symmetries. For a 4 ⁢ N {4N} -carpet F , let { F n } n ≥ 0 {\{F_{n}\}_{n\geq 0}} be the natural decreasing sequence of compact pre-fractal approximations with ⋂ n F n = F {\bigcap_{n}F_{n}=F} . On each F n {F_{n}} , let ℰ ⁢ ( u , v ) = ∫ F N ∇ ⁡ u ⋅ ∇ ⁡ v ⁢ d ⁢ x {\mathcal{E}(u,v)=\int_{F_{N}}\nabla u\cdot\nabla v\,dx} be the classical Dirichlet form and u n {u_{n}} be the unique harmonic function on F n {F_{n}} satisfying a mixed boundary value problem corresponding to assigning a constant potential between two specific subsets of the boundary. Using a method introduced by [M. T. Barlow and R. F. Bass,On the resistance of the Sierpiński carpet, Proc. Roy. Soc. Lond. Ser. A 431 (1990), no. 1882, 345–360], we prove a resistance estimate of the following form: there is ρ = ρ ⁢ ( N ) > 1 {\rho=\rho(N)>1} such that ℰ ⁢ ( u n , u n ) ⁢ ρ n {\mathcal{E}(u_{n},u_{n})\rho^{n}} is bounded above and below by constants independent of n . Such estimates have implications for the existence and scaling properties of Brownian motion on F . 

Abstract Processes controlling dissolved barium (dBa) were investigated along the GEOTRACES GA03 North Atlantic and GP16 Eastern Tropical Pacific transects, which traversed similar physical and biogeochemical provinces. Dissolved Ba concentrations are lowest in surface waters (∼35–50 nmol kg⁻¹) and increase to 70–80 and 140–150 nmol kg⁻¹in deep waters of the Atlantic and Pacific transects, respectively. Using water mass mixing models, we estimate conservative mixing that accounts for most of dBa variability in both transects. To examine nonconservative processes, particulate excess Ba (pBa_xs) formation and dissolution rates were tracked by normalizing particulate excess²³⁰Th activities. Th‐normalized pBa_xsfluxes, with barite as the likely phase, have subsurface maxima in the top 1,000 m (∼100–200 μmol m⁻² year⁻¹average) in both basins. Barite precipitation depletes dBa within oxygen minimum zones from concentrations predicted by water mass mixing, whereas inputs from continental margins, particle dissolution in the water column, and benthic diffusive flux raise dBa above predications. Average pBa_xsburial efficiencies along GA03 and GP16 are ∼37% and 17%–100%, respectively, and do not seem to be predicated on barite saturation indices in the overlying water column. Using published values, we reevaluate the global freshwater dBa river input as 6.6 ± 3.9 Gmol year⁻¹. Estuarine mixing processes may add another 3–13 Gmol year⁻¹. Dissolved Ba inputs from broad shallow continental margins, previously unaccounted for in global marine summaries, are substantial (∼17 Gmol year⁻¹), exceeding terrestrial freshwater inputs. Revising river and shelf dBa inputs may help bring the marine Ba isotope budget more into balance.